N-coordinated Ru(ii) catalyzed solvent freeN-alkylation of primary amines with alcohols through borrowing hydrogen strategy

Author:

Patel Bhavya1ORCID,Ranjan Rishi2ORCID,Chauhan Nimesh R.1ORCID,Mukhopadhyay Suman2ORCID,Choudhury Angshuman Roy3,Vyas Komal M.1ORCID

Affiliation:

1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar 388120, India

2. Department of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Simrol, Indore 453552, India

3. Department of Chemical Sciences, Indian Institute of Science Education and Research, Mohali, Sector 81, S. A. S. Nagar, Manauli PO, Mohali, Panjab 140306, India

Abstract

The catalytic efficacy of N-coordinated Ru(ii)-complexes has been examined forN-alkylation of amines in a benign and solvent-free conditions. Electron deficient [Ru-1] led to superior catalytic conversion due to Metal Ligand Cooperation.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference94 articles.

1. S. A.Lawrence , Amines: synthesis, properties, and applications , Cambridge University Press , New York , 2004

2. Amino group chemistry: from synthesis to the life sciences , ed. A. Ricci , John Wiley & Sons, Inc , Weinheim , 2008

3. V. Researches regarding the molecular constitution of the volatile organic bases

4. J.McMurry , Organic chemistry , Cengage Brooks/Cole , Belmont, CA , 7th enhanced ed., 2010

5. Chiral Amine Synthesis - Recent Developments and Trends for Enamide Reduction, Reductive Amination, and Imine Reduction

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