N-Alkylation of aromatic amines with alcohols by using a commercially available Ru complex under mild conditions

Author:

Mocci Rita1ORCID,Atzori Luciano1ORCID,Baratta Walter2ORCID,De Luca Lidia3ORCID,Porcheddu Andrea1ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, Cittadella Universitaria, S.S. 554 bivio per Sestu, 09042 Monserrato (CA), Italy

2. Dipartimento di Scienze Agroalimentari, Ambientali e Animali, Università degli Studi di Udine, via delle Scienze 206, 33100 Udine, Italy

3. Dipartimento di Scienze Chimiche, FIsiche, Matematiche e Naturali, Università degli Studi di Sassari, via Vienna 2, 07100 Sassari, Italy

Abstract

An N-alkylation procedure has been developed under very mild conditions using a known commercially available Ru-based catalyst.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference56 articles.

1. S. A.Lawrence , Amines: Synthesis Properties, and Applications , Cambridge University Press , 2004

2. A. S.Travis , The Chemistry of Anilines , ed. Z. Rappoport , Wiley-Interscience , 2007 , vol. 1 , p. 717

3. The Catalytic Amination of Alcohols

4. Borrowing Hydrogen Amination Reactions: A Complex Analysis of Trends and Correlations of the Various Reaction Parameters

5. Hydrogen Autotransfer in the N-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

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