A covalent organic framework with electrodeposited copper nanoparticles – a desirable catalyst for the Ullmann coupling reaction

Author:

Chandran Chandana1,Singh Himan Dev1,Leo Liya S.1,Shekhar Pragalbh1,Rase Deepak1,Chakraborty Debanjan1ORCID,Vinod Chathakudath P.2ORCID,Vaidhyanathan Ramanathan13ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science Education and Research, Pune, Maharashtra-411008, India

2. CSIR-NCL, Catalysis and Inorganic Chemistry Division, Pune, Maharashtra-411008, India

3. Centre for Energy Science, Indian Institute of Science Education and Research, Pune, Maharashtra-411008, India

Abstract

Electrochemical deposition from an electrolyte containing Cu2+ loads Cu(0) nanoparticles (3.34 wt%) into a COF, making them resemble a single-site catalyst. This Cu@COF serves as an excellent heterogeneous catalyst for multi-fold Ullmann coupling reactions.

Funder

Indian Institute of Science Education and Research Pune

Science and Engineering Research Board

Ministry of Education, India

Department of Science and Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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