Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)–H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles-Reference-Cited by-同舟云学术

Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)–H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles

Published:2017 Issue:51 Volume:53 Page:6914-6917
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Xing Qi¹²³⁴⁵,Lv Hui¹²³⁴⁵,Xia Chungu¹²³⁴⁵,Li Fuwei¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation

2. Lanzhou Institute of Chemical Physics

3. Chinese Academy of Sciences

4. Lanzhou 730000

5. China

Abstract

We report the first intermolecular carbonylative cross-coupling of heteroaryl C(sp²)–H bonds with amines using oxygen as the green oxidant.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC03274A

Reference40 articles.

1. Analysis of the reactions used for the preparation of drug candidate molecules

2. Metal-catalysed approaches to amide bond formation

3. Rethinking amide bond synthesis

4. Catalytic amide formation from non-activated carboxylic acids and amines

5. Synthetic Applications of Palladium Catalysed Carbonylation of Organic Halides

Cited by 20 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. C–H/C–H Aromative carbonylation of diarylalkynes enabled palladium-catalyzed by 6-endo-dig carbocyclization;Journal of Catalysis;2024-09

2. Metal-free coordination of porphyrin-based porous organic polymers for efficient photocatalytic oxidative coupling of amines under visible light;Molecular Catalysis;2023-07

3. From intramolecular cyclization to intermolecular hydrolysis: TMSCF₂Br-enabled carbonylation of aldehydes/ketones and amines to α-hydroxyamides;Organic Chemistry Frontiers;2023

4. Rhodium-catalyzed aminoacylation of alkenes via carbonylative C–H activation toward poly(hetero)cyclic alkylarylketones;Organic Chemistry Frontiers;2023

5. Synthesis of unprotected glyco-alkynones via molybdenum-catalyzed carbonylative Sonogashira cross-coupling reaction;RSC Advances;2022