The porphyrin center as a regulator for metal–ligand covalency and π hybridization in the entire molecule-Reference-Cited by-同舟云学术

The porphyrin center as a regulator for metal–ligand covalency and π hybridization in the entire molecule

Published:2021 Issue:43 Volume:23 Page:24765-24772
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Büchner Robby¹^ORCID,Fondell Mattis²^ORCID,Haverkamp Robert²^ORCID,Pietzsch Annette²^ORCID,Vaz da Cruz Vinícius²^ORCID,Föhlisch Alexander¹²^ORCID

Affiliation:

1. Institute of Physics and Astronomy, University of Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Potsdam, Germany

2. Institute for Methods and Instrumentation for Synchrotron Radiation Research, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Str. 15, 12489 Berlin, Germany

Abstract

The porphyrin center is shown to control both the covalency of the central complex and π hybridization with peripheral substituents.

Funder

H2020 European Research Council

Helmholtz-Zentrum Berlin für Materialien und Energie

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03944J

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