Metal–ligand delocalization of iron and cobalt porphyrin complexes in aqueous solutions probed by soft X-ray absorption spectroscopy-Reference-Cited by-同舟云学术

Metal–ligand delocalization of iron and cobalt porphyrin complexes in aqueous solutions probed by soft X-ray absorption spectroscopy

Published:2024 Issue: Volume: Page:
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nagasaka Masanari¹²^ORCID,Tsuru Shota³⁴^ORCID,Yamada Yasuyuki⁵⁶^ORCID

Affiliation:

1. Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan

2. Graduate Institute for Advanced Studies, SOKENDAI, Myodaiji, Okazaki 444-8585, Japan

3. Lehrstuhl für Theoretische Chemie, Ruhr-Universität Bochum, D-44780 Bochum, Germany

4. RIKEN Center for Computational Science, RIKEN, Kobe 650-0047, Japan

5. Department of Chemistry, Graduate School of Science, Nagoya University, Nagoya 464-8602, Japan

6. Research Center for Materials Science, Nagoya University, Nagoya 464-8602, Japan

Abstract

Metal–ligand delocalization of metalloporphyrins in aqueous solutions was investigated by soft X-ray absorption spectroscopy, indicating that the coordination structures can be analyzed from ligand sides at nitrogen K-edges.

Funder

Japan Society for the Promotion of Science

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP02140A

Reference49 articles.

1. The green pigment of life

2. Supramolecular Chemistry of Metalloporphyrins

3. Spin-state/stereochemical relationships in iron porphyrins: implications for the hemoproteins

4. J. K. M.Sanders , N.Bampos , Z.Clyde-Watson , S. L.Darling , J. C.Hawley , H.-J.Kim , C. C.Mak and S. J.Webb , in The Porphyrin Handbook, Inorganic, organometallic and coordination chemistry , ed. K. M. Kadish , K. M. Smith and R. Guilard , Academic Press , San Diego, CA , 2000 , vol. 3, pp. 1–48

5. L.Cheng and G. B.Richter-Addo , in The Porphyrin Handbook, Biochemistry and binding: activation of small molecules , ed. K. M. Kadish , K. M. Smith and R. Guilard , Academic Press , San Diego, CA , 2000 , vol. 4, pp. 219–291