Theoretical study on the reaction of triallyl isocyanurate in the UV radiation cross-linking of polyethylene

Author:

Zhao Hong12345,Chen Junqi12345,Zhang Hui12345ORCID,Shang Yan12345,Wang Xuan12345,Han Baozhong12345,Li Zesheng678910ORCID

Affiliation:

1. Key Laboratory of Engineering Dielectrics and Its Application of Ministry of Education

2. College of Chemical and Environmental Engineering

3. Harbin University of Science and Technology

4. Harbin

5. People's Republic of China

6. Key Laboratory of Cluster Science of Ministry of Education

7. School of Chemistry

8. Beijing Institute of Technology

9. Beijing

10. P. R. China

Abstract

Herein, a theoretical investigation on the reaction potential energy surface information of triallyl isocyanurate (TAIC) in the UV radiation cross-linking process of polyethylene is conducted at the B3LYP/6-311+G(d,p) level for the production of high voltage cable insulation materials.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference32 articles.

1. Photocross-linking of low-density polyethylene. I. Kinetics and reaction parameters

2. B. Qu , W.Bao, Q.Wu and W.Shi, Recent Developments on Photoinitiated Crosslinking of Polyethylene and Its Applications for Manufacturing Insulated Wire and Cable, IEEE International Conference on the Properties and Applications of Dielectric Materials, Harbin, 2009, pp. 33–36

3. Photoinitiated crosslinking of low density polyethylene. IV: Continuous extrusion application

4. Photoinitiating characteristics of benzophenone derivatives as new initiators in the photocrosslinking of polyethylene

5. Photoinitiated crosslinking of low density polyethylene I: Reaction and kinetics

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