Relevance of Ge incorporation to control the physical behaviour of point defects in kesterite

Author:

Ratz Thomas12ORCID,Nguyen Ngoc Duy1ORCID,Brammertz Guy3ORCID,Vermang Bart234ORCID,Raty Jean-Yves1

Affiliation:

1. CESAM | Q-MAT | Solid State Physics, Interfaces and Nanostructures, University of Liège, Allée du Six Août 19, B-4000 Liège, Belgium

2. Institute for Material Research (IMO), Hasselt University, Agoralaan gebouw H, B-3590 Diepenbeek, Belgium

3. IMEC Division IMOMEC | Partner in Solliance, Wetenschapspark 1, B-3590 Diepenbeek, Belgium

4. Energyville, Thor Park 8320, B-3600 Genk, Belgium

Abstract

Ge-containing kesterites for PV applications demonstrated their effectiveness in improving the cell VOC. The physical behaviour of defects is found to be a key mechanism, with the GeZn antisite appearing less detrimental than its SnZn counterpart.

Funder

Fonds De La Recherche Scientifique – FNRS

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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