Quantifying the influence of 3d–4s mixing on linearly coordinated metal-ions by L<sub>2,3</sub>-edge XAS and XMCD-Reference-Cited by-同舟云学术

Quantifying the influence of 3d–4s mixing on linearly coordinated metal-ions by L_2,3-edge XAS and XMCD

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Huzan Myron S.¹²^ORCID,Burrow Timothy G.¹²^ORCID,Fix Manuel³,Breitner Franziska A.³,Chong Sut Kei¹²,Bencok Peter⁴,Aramini Matteo⁴,Jesche Anton³,Baker Michael L.¹²^ORCID

Affiliation:

1. Department of Chemistry, The University of Manchester, Manchester, M13 9PL, UK

2. The University of Manchester at Harwell, Diamond Light Source, Harwell Campus, OX11 0DE, UK

3. EP VI, Center for Electronic Correlations and Magnetism, Institute of Physics, University of Augsburg, D-86159 Augsburg, Germany

4. Diamond Light Source, Harwell Science and Innovation Campus, Chilton, Didcot, OX11 0DE, UK

Abstract

X-ray absorption spectroscopy and dichroism are applied to probe the effect of 3d–4s mixing on electronic structure and magnetism for linearly coordinated Mn, Fe, Co, Ni and Cu.

Funder

Diamond Light Source

Royal Society of Chemistry

Science and Technology Facilities Council

Engineering and Physical Sciences Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06308A

Reference52 articles.

1. Magnetic blocking in a linear iron(I) complex

2. A linear cobalt(II) complex with maximal orbital angular momentum from a non-Aufbau ground state

3. A 9.2-GHz clock transition in a Lu(II) molecular spin qubit arising from a 3,467-MHz hyperfine interaction

4. C. G.Werncke and A. G.Gómez , Encyclopedia of Inorganic and Bioinorganic Chemistry , 2022 , pp. 1–30

5. Single-ion magnetism in the extended solid-state: insights from X-ray absorption and emission spectroscopy