Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst-Reference-Cited by-同舟云学术

Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst

Published:2018 Issue:13 Volume:8 Page:6910-6914
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Clot-Almenara Lidia¹²³⁴^ORCID,Rodríguez-Escrich Carles¹²³⁴^ORCID,Pericàs Miquel A.¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ)

2. The Barcelona Institute of Science and Technology

3. 43007 Tarragona

4. Spain

5. Departament de Química Inorgànica i Orgànica

Abstract

A polystyrene-supported, recyclable, BINOL-derived chiral phosphoric acid has been applied to the desymmetrization of meso-diones to produce enantioenriched cyclohexenones.

Funder

Ministerio de Economía y Competitividad

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA13471A

Reference71 articles.

1. 307. Experiments on the synthesis of substances related to the sterols. Part II. A new general method for the synthesis of substituted cyclohexenones

2. Acid-catalyzed Robinson Annelations

3. Asymmetric synthesis of bicyclic intermediates of natural product chemistry

4. Total syntheses of optically active 19-nor steroids. (+)-Estr-4-ene-3,17-dione and (+)-13.beta.-ethylgon-4-ene-3,17-dione

Cited by 18 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Enantioselective Flow Synthesis of a Tetrahydroquinoline SERM Enabled by Immobilized Chiral Phosphoric Acid Catalysis and Diboronic Acid Mediated Selective Nitro Reduction;Advanced Synthesis & Catalysis;2024-01-26

2. A robust heterogeneous chiral phosphoric acid enables multi decagram scale production of optically active N,S-ketals;Green Chemistry;2024

3. A Telescoped Continuous Flow Enantioselective Process for Accessing Intermediates of 1-Aryl-1,3-diols as Chiral Building Blocks;The Journal of Organic Chemistry;2023-10-16

4. Polymer‐Supported Phosphoric‐Acid Catalysed Enantioselective Pictet‐Spengler Cyclisation for the Synthesis of Quaternary Tryptolines in Batch/Continuous Flow;Advanced Synthesis & Catalysis;2023-01-24

5. Semi-heterogeneous asymmetric organocatalysis: Covalent immobilization of BINOL-derived chiral phosphoric acid (TRIP) to polystyrene brush grafted on SiO2 nanoparticles;Journal of Catalysis;2022-12