Exploring cycling induced crystallographic change in NMC with X-ray diffraction computed tomography

Author:

Daemi Sohrab R.12345ORCID,Tan Chun12345ORCID,Vamvakeros Antonis678910ORCID,Heenan Thomas M. M.12345ORCID,Finegan Donal P.111213ORCID,Di Michiel Marco6789ORCID,Beale Andrew M.101415516ORCID,Cookson James17185,Petrucco Enrico17185ORCID,Weaving Julia S.12345,Jacques Simon1014155,Jervis Rhodri12345ORCID,Brett Dan J. L.12345ORCID,Shearing Paul R.12345ORCID

Affiliation:

1. Electrochemical Innovation Lab

2. Department of Chemical Engineering

3. University College London

4. London WC1E 7JE

5. UK

6. ESRF

7. The European Synchrotron

8. 38000 Grenoble

9. France

10. Finden Limited

11. National Renewable Energy Laboratory

12. Golden

13. USA

14. Merchant House

15. Abingdon

16. Department of Chemistry

17. Johnson Matthey Technology Centre

18. Reading RG4 9NH

Abstract

This study presents the application of XRD-CT combined with FIB-SEM to analyze the crystal dimensions of LiNi0.33Mn0.33Co0.33O2 electrodes and spatially localise the change in unit cell dimensions as a result of electrochemical cycling.

Funder

Engineering and Physical Sciences Research Council

Royal Academy of Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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