Can acyclic conformational control be achieved via a sulfur–fluorine gauche effect?-Reference-Cited by-同舟云学术

Can acyclic conformational control be achieved via a sulfur–fluorine gauche effect?

Published:2015 Issue:6 Volume:6 Page:3565-3571
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Thiehoff C.¹²³⁴⁵,Holland M. C.¹²³⁴⁵,Daniliuc C.¹²³⁴⁵,Houk K. N.⁶⁷⁸⁹,Gilmour R.¹²³⁴⁵

Affiliation:

1. Organisch Chemisches Institut, and Excellence Cluster EXC 1003

2. Cells in Motion

3. Westfälische Wilhelms-Universität Münster

4. Münster

5. Germany

6. Department of Chemistry and Biochemistry

7. University of California Los Angeles

8. Los Angeles 90095-1569

9. USA

Abstract

Herein detailed conformational analyses of β-fluorosulfides, -sulfoxides and -sulfones are disclosed, thus extending the scope of the fluorine gauche effect to the 3^rd Period (X = SR, SOR, SO₂R; ϕ_FCCS ≈ 60°).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00871A

Reference66 articles.

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5. Fluorine Conformational Effects in Organocatalysis: An Emerging Strategy for Molecular Design

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