Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid-Reference-Cited by-同舟云学术

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Accumulation, Characterization and Reactivity of Chiral Ammonium‐Carboxonium Dications in Superacid

Published:2024-04-25 Issue:23 Volume:63 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Berrino Emanuela¹^ORCID,Cantin Thomas¹,Artault Maxime¹^ORCID,Beck Stefanie²,Jessen Christoph²,Marrot Jérôme³,Guégan Frédéric¹^ORCID,Mingot Agnès¹^ORCID,Kornath Andreas²,Thibaudeau Sébastien¹^ORCID

Affiliation:

1. IC2MP UMR CNRS 7285 Université de Poitiers 4 rue Michel Brunet 86073 Poitiers cedex 9 France

2. Department of Chemistry Ludwig-Maximilian University of Munich Butenandtstr. 5–13 D-81377 München Germany

3. UMR CNRS 8180 45 avenue des États-Unis 78035 Versailles Cedex France

Abstract

AbstractThe accumulation of chiral ammonium‐oxocarbenium dications in superacid is evidenced by low‐temperature NMR spectroscopy, X‐ray diffraction analysis and confirmed by DFT calculations. Its potential for the diastereoselective remote hydrofunctionalization of non‐activated alkene is also explored.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202404066

Reference113 articles.

1. Reference Scales for the Characterization of Cationic Electrophiles and Neutral Nucleophiles,

3. Catalytic, Asymmetric Halofunctionalization of Alkenes-A Critical Perspective

4. Recent Advances in Catalytic Sequential Reactions Involving Hydroelement Addition to Carbon–Carbon Multiple Bonds

5. Catalytic Markovnikov and anti-Markovnikov Functionalization of Alkenes and Alkynes: Recent Developments and Trends

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