How intramolecular hydrogen bonding (IHB) controls the C–ON bond homolysis in alkoxyamines-Reference-Cited by-同舟云学术

How intramolecular hydrogen bonding (IHB) controls the C–ON bond homolysis in alkoxyamines

Published:2017 Issue:39 Volume:15 Page:8425-8439
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Audran Gérard¹²³⁴⁵,Bikanga Raphael⁶⁷⁸,Brémond Paul¹²³⁴⁵,Edeleva Mariya⁹¹⁰¹¹^ORCID,Joly Jean-Patrick¹²³⁴⁵,Marque Sylvain R. A.¹²³⁴⁵^ORCID,Nkolo Paulin¹²³⁴⁵,Roubaud Valérie¹²³⁴⁵

Affiliation:

1. Aix Marseille Univ

2. CNRS

3. ICR

4. UMR 7273

5. 13397 Marseille Cedex 20

6. Laboratoire de Substances Naturelles et de Synthèse Organométalliques Université des Sciences et Techniques de Masuku

7. B.P. 943 Franceville

8. Gabon

9. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS

10. 630090 Novosibirsk

11. Russia

Abstract

IHB between alkyl and nitroxyl fragments affords striking changes in k_d, affording a nice control of the C–ON bond homolysis.

Funder

Agence Nationale de la Recherche

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB02223A

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