Unsymmetrical relay C–H alkenylation and [2 + 2] cycloaddition of<i>N</i>-arylsydnones with allenyl acetates leading to quinoline-fused cyclobutanes-Reference-Cited by-同舟云学术

Unsymmetrical relay C–H alkenylation and [2 + 2] cycloaddition ofN-arylsydnones with allenyl acetates leading to quinoline-fused cyclobutanes

Published:2023 Issue:5 Volume:10 Page:1191-1197
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Song Xia¹,Wang Kelin¹,Zhang Xinying¹^ORCID,Fan Xuesen¹^ORCID

Affiliation:

1. School of Environment, School of Chemistry and Chemical Engineering, Key Laboratory for Yellow River and Huai River Water Environmental Pollution Control, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Henan Normal University, Xinxiang, Henan 453007, China

Abstract

In this paper, we present a direct, effective and atom-economical access toward quinoline-fused cyclobutane derivatives through Rh(iii)-catalyzed cascade reactions ofN-arylsydnones with allenyl acetates.

Funder

Natural Science Foundation of Henan Province

Henan Key Laboratory of Organic Functional Molecules and Drug Innovation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01795D

Reference54 articles.

1. Emergence of diversity and stereochemical outcomes in the biosynthetic pathways of cyclobutane-centered marine alkaloid dimers