Palladium catalyzed C–H bond acetoxylation: isoxazolinyl as a directing group
Author:
Affiliation:
1. Key Laboratory of Radiopharmaceuticals
2. Ministry of Education
3. College of Chemistry
4. Beijing Normal University
5. Beijing 100875
Abstract
Pd(OAc)2-catalyzed acetoxylations of 3-aryl or 3-alkyl groups mounted on a 2-isoxazoline ring were studied. Substituent effect on reactivity and regioselectivity was examined. The acetoxylation was applied to the synthesis of useful intermediates.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA07793E
Reference94 articles.
1. Ru-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic Aspects
2. σ-Chelation-directed C–H functionalizations using Pd(ii) and Cu(ii) catalysts: regioselectivity, stereoselectivity and catalytic turnover
3. C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents
4. Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
5. Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions
Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Recent progress in catalytic acyloxylation of C(sp 3 )‐H bonds;Applied Organometallic Chemistry;2022-01-05
2. Transition Metal‐Mediated Functionalization of Isoxazoles: A Review;Asian Journal of Organic Chemistry;2021-11-08
3. Mild synthesis of isoxazoline derivatives via an efficient [4 + 1] annulation reaction of transient nitrosoalkenes and sulfur ylides;Scientific Reports;2021-01-22
4. Hypervalent iodine promoted ortho diversification: 2-aryl benzimidazole, quinazoline and imidazopyridine as directing templates;Organic & Biomolecular Chemistry;2020
5. Transition Metal‐Catalyzed Reactions with Iodine( III ) Reagents;PATAI'S Chemistry of Functional Groups;2018-12-10
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3