Self-assembly of Pt(<scp>ii</scp>)-tetrakis(pentafluorophenyl)porphyrin <i>via</i> F⋯F interaction for efficient cocatalyst-free photocatalytic hydrogen evolution-Reference-Cited by-同舟云学术

Self-assembly of Pt(ii)-tetrakis(pentafluorophenyl)porphyrin via F⋯F interaction for efficient cocatalyst-free photocatalytic hydrogen evolution

Published:2024 Issue:5 Volume:12 Page:2924-2931
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Bodedla Govardhana Babu¹²³^ORCID,Piradi Venkatesh³,Thor Waygen³^ORCID,Wong Ka-Leung³^ORCID,Zhu Xunjin³^ORCID,Wong Wai-Yeung¹²^ORCID

Affiliation:

1. Department of Applied Biology & Chemical Technology, Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hong Kong, P. R. China

2. The Hong Kong Polytechnic University Shenzhen Research Institute, Shenzhen 518057, P. R. China

3. Department of Chemistry, Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, P. R. China

Abstract

Self-assembled PtPFTPP via dominant F⋯F interaction restricts aggregation caused quenching (ACQ) in the solid state. This leads to longer-lived photoexcited triplet and thereby higher photocatalytic hydrogen evolution rate of 400 μmol g−1 h−1 compared to self-assembled PtTPP with noticeable ACQ.

Funder

Hong Kong Baptist University

National Natural Science Foundation of China

Hong Kong Polytechnic University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA05389J

Reference50 articles.

1. Self-Assembled Naphthalimide-Substituted Porphyrin Nanowires for Photocatalytic Hydrogen Evolution