Distonic radical anion species in cysteine oxidation processes-Reference-Cited by-同舟云学术

Distonic radical anion species in cysteine oxidation processes

Published:2020 Issue:31 Volume:22 Page:17554-17558
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Qin Zhengbo¹²³⁴^ORCID,Hou Gao-Lei⁵⁶⁷⁸^ORCID,Yang Zheng⁵⁶⁷⁸,Valiev Marat⁹⁶⁷⁸^ORCID,Wang Xue-Bin⁵⁶⁷⁸^ORCID

Affiliation:

1. Anhui Province Key Laboratory of Optoelectric Materials Science and Technology

2. Anhui Normal University

3. Wuhu

4. China

5. Physical Sciences Division

6. Pacific Northwest National Laboratory

7. Richland

8. USA

9. Environmental Molecular Sciences Laboratory

Abstract

In contrast to the first reversible oxidation step being associated with sulfinate species, a novel distonic radical anion, ^•OS–CH₂CH(NH₂)–COO⁻ has been identified with an inverted SOMO–HOMO energy order that can be restored via protonation.

Funder

National Natural Science Foundation of China

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02165B

Reference40 articles.

1. Expanding the functional diversity of proteins through cysteine oxidation

2. Cysteine-Mediated Redox Signaling: Chemistry, Biology, and Tools for Discovery