Zn-mediated electrochemical α-alkylation of amines with halogenated alkanes through convergent paired electrolysis-Reference-Cited by-同舟云学术

Zn-mediated electrochemical α-alkylation of amines with halogenated alkanes through convergent paired electrolysis

Published:2023 Issue:18 Volume:25 Page:7356-7361
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhan Xiaoyu¹,Liu Hongyu¹,Liu Rui¹,Huang Yanmin²,Peng Yungui¹^ORCID

Affiliation:

1. Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

2. College of Chemistry and Life Science, Guangxi Teachers Education University, Nanning 530001, China

Abstract

A green and sustainable electrochemical strategy for α-alkylation of tertiary amines with halogenated alkanes was established through the interaction of imine ions generated at the anode with alkyl zinc reagents generated at the cathode.

Funder

Southwest University

National Natural Science Foundation of China

Natural Science Foundation of Chongqing

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC01325A

Reference49 articles.

1. The Barbier–Grignard-type arylation of aldehydes using unactivated aryl iodides in water

2. Zinc-mediated α-regioselective Barbier-type cinnamylation reactions of aldehydes, ketones and esters

3. The Barbier−Grignard-Type Carbonyl Alkylation Using Unactivated Alkyl Halides in Water

4. Nonradical Zinc−Barbier Reaction for Diastereoselective Synthesis of Vicinal Amino Alcohols

5. The continuous flow Barbier reaction: an improved environmental alternative to the Grignard reaction?

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