A photo-driven traceless group directed electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation tandem reaction: access to 1-allyl/benzyl-3,4-dihydroisoquinoline

Author:

Zhang Tao1,Ren Xinxin1,Wang Bin1ORCID,Jin Weiwei1,Xia Yu1ORCID,Wu Shaofeng1,Liu Chenjiang123ORCID,Zhang Yonghong13ORCID

Affiliation:

1. Urumqi Key Laboratory of Green Catalysis and Synthesis Technology, Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry, Xinjiang University, Urumqi 830017, P. R. China

2. College of Future Technology, Xinjiang University, Urumqi 830017, P. R. China

3. Institute of materia medica, Xinjiang University, Urumqi 830017, P. R. China

Abstract

A metal-free and mild one pot protocol for the traceless group directed and electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation of arylazo-protected tetrahydroisoquinolines with benzyl/allyl bromide is reported.

Publisher

Royal Society of Chemistry (RSC)

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