Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies-Reference-Cited by-同舟云学术

Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies

Published:2017 Issue:4 Volume:7 Page:848-857
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kee J. W.¹²³⁴⁵,Shao H.¹²³⁴⁵,Kee C. W.¹²³⁴⁵^ORCID,Lu Y.¹²³⁴⁵,Soo H. S.¹²³⁴⁵^ORCID,Tan C.-H.¹²³⁴⁵

Affiliation:

1. Division of Chemistry and Biological Chemistry

2. School of Physical and Mathematical Sciences

3. 21 Nanyang Link

4. Nanyang Technological University

5. 637371 Singapore

Abstract

Nanosecond TAS and DFT calculations reveal mechanistic insights for photoredox fluorination of aliphatic C–H bonds and evidence of an anthraquinone–Selectfluor® exciplex.

Funder

Nanyang Technological University

National Research Foundation-Prime Minister's office, Republic of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CY/C6CY02484J

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