Synergetic spin singlet–quintet switching and luminescence in mononuclear Fe(<scp>ii</scp>) 1,3,4-oxadiazole tetradentate chelates with NCBH<sub>3</sub> co-ligand-Reference-Cited by-同舟云学术

Synergetic spin singlet–quintet switching and luminescence in mononuclear Fe(ii) 1,3,4-oxadiazole tetradentate chelates with NCBH₃ co-ligand

Published:2023 Issue:37 Volume:52 Page:13181-13189
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sundaresan Sriram¹,Becker Jens-Georg¹,Eppelsheimer Julian¹,Sedykh Alexander E.²^ORCID,Carrella Luca M.¹,Müller-Buschbaum Klaus²,Rentschler Eva¹^ORCID

Affiliation:

1. Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10–14, 55128 Mainz, Germany

2. Institute of Inorganic and Analytical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, 35392, Giessen, Germany

Abstract

First mononuclear 1,3,4-oxadiazole based multifunctional Fe(ii) complex (C1) and its Zn(ii) analogue (C2) are reported. C1 shows SCO both in solid state and in solution at 207 K and 357 K respectively. Its SCO-luminescence interplay is investigated.

Funder

Johannes Gutenberg-Universität Mainz

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02420B

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