A combined theoretical and experimental approach to determine the right choice of co-ligand to impart spin crossover in Fe(<scp>ii</scp>) complexes based on 1,3,4-oxadiazole ligands-Reference-Cited by-同舟云学术

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A combined theoretical and experimental approach to determine the right choice of co-ligand to impart spin crossover in Fe(ii) complexes based on 1,3,4-oxadiazole ligands

Published:2024 Issue:24 Volume:53 Page:10303-10317
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sundaresan Sriram¹^ORCID,Eppelsheimer Julian¹,Gera Esha²,Wiener Lukas¹,Carrella Luca M.¹^ORCID,Vignesh Kuduva R.²^ORCID,Rentschler Eva¹^ORCID

Affiliation:

1. Department Chemie, Johannes-Gutenberg-Universität Mainz, Duesbergweg 10–14, 55128 Mainz, Germany

2. Department of Chemical Scienaces, Indian Institute of Science Education Research (IISER) Mohali, Sector-81, Knowledge City, S.A.S. Nagar, Mohali 140306, Punjab, India

Abstract

It is discussed why for the Fe(ii) complexes [Fe(LTetra-Py/Ph-ODA)(NCE)] with E = S, Se and BH3 only the latter revealed SCO.

Funder

Johannes Gutenberg-Universität Mainz

Council of Scientific and Industrial Research, India

University Grants Commission

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01141D

Reference51 articles.

1. Iron chemistry at the service of life

2. The Ubiquity of Iron

3. The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

4. Über die magnetische Susceptibilität der komplexen Verbindungen

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