Successive C–C bond cleavage, fluorination, trifluoromethylthio- and pentafluorophenylthiolation under metal-free conditions to provide compounds with dual fluoro-functionalization-Reference-Cited by-同舟云学术

Successive C–C bond cleavage, fluorination, trifluoromethylthio- and pentafluorophenylthiolation under metal-free conditions to provide compounds with dual fluoro-functionalization

Published:2016 Issue:3 Volume:7 Page:2106-2110
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Saidalimu Ibrayim¹²³⁴,Suzuki Shugo⁵²³⁴,Tokunaga Etsuko¹²³⁴,Shibata Norio¹²³⁴⁵

Affiliation:

1. Department of Nanopharmaceutical Sciences

2. Nagoya Institute of Technology

3. Nagoya 466-8555

4. Japan

5. Department of Frontier Materials

Abstract

The selective C–C bond cleavage and simultaneous formation of two C–F bonds and one C–S bond with DAST, CF₃-DAST under metal-free/catalyst-free conditions is disclosed.

Funder

Japan Science and Technology Agency

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04208A

Reference44 articles.

1. G. Dong , C–C Activation (Topics in Current Chemistry), Springer-Verlag, Berlin, Heidelberg, 2014

2. Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals