Pressure-induced Jahn–Teller switching in a Mn12 nanomagnet

Author:

Parois Pascal12345,Moggach Stephen A.6789,Sanchez-Benitez Javier6789,Kamenev Konstantin V.6789,Lennie Alistair R.10119,Warren John E.10119,Brechin Euan K.6789,Parsons Simon6789,Murrie Mark12345

Affiliation:

1. WestCHEM

2. Department of Chemistry

3. University of Glasgow

4. University Avenue

5. Glasgow

6. School of Chemistry and Centre for Science at Extreme Conditions

7. University of Edinburgh

8. Edinburgh

9. UK

10. STFC Daresbury Laboratory

11. Cheshire

Abstract

Using high pressure diffraction and magnetic data, we observe reversible switching of a Mn12 nanomagnet from the 100% fast-relaxing species to the 100% slow-relaxing species, by flipping the misaligned Jahn–Teller axis.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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