Using internal strain and mass to modulate Dy⋯Dy coupling and relaxation of magnetization in heterobimetallic metallofullerenes DyM2N@C80 and Dy2MN@C80 (M = Sc, Y, La, Lu)

Author:

Hao Yajuan12,Velkos Georgios1,Schiemenz Sandra1,Rosenkranz Marco1,Wang Yaofeng1,Büchner Bernd1,Avdoshenko Stanislav M.1ORCID,Popov Alexey A.1ORCID,Liu Fupin1ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research (IFW Dresden), 01069 Dresden, Germany

2. School of Electrical and Mechanical Engineering, Pingdingshan University, Pingdingshan 467000, China

Abstract

Relaxation of magnetization in DyM2N@C80 and Dy2MN@C80 (M = Sc, Y, La, Lu) series correlates, respectively, with the mass and size of the diamagnetic metal M.

Funder

China Scholarship Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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