Synthesis of bicyclo[3.1.0]hexanes by (3 + 2) annulation of cyclopropenes with aminocyclopropanes
Author:
Affiliation:
1. Laboratory of Catalysis and Organic Synthesis
2. Institut des Sciences et Ingénierie Chimique
3. Ecole Polytechnique Fédérale de Lausanne
4. Lausanne
5. Switzerland
Abstract
(3 + 2) annulation of cyclopropenes and aminocyclopropanes under mild photoredox conditions leading to bicyclo[3.1.0]hexanes with high diastereoselectivity for fluorinated derivatives.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
École Polytechnique Fédérale de Lausanne
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC03790J
Reference100 articles.
1. 2-Substitution of Adenine Nucleotide Analogues Containing a Bicyclo[3.1.0]hexane Ring System Locked in a Northern Conformation: Enhanced Potency as P2Y1 Receptor Antagonists
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3. (1aR,5aR)1a,3,5,5a-Tetrahydro-1H-2,3-diaza-cyclopropa[a]pentalene-4-carboxylic Acid (MK-1903): A Potent GPR109a Agonist that Lowers Free Fatty Acids in Humans
4. Nardoaristolones A and B, Two Terpenoids with Unusual Skeletons from Nardostachys chinensis Batal
5. Cycloeudesmol, an antibiotic cyclopropane containing sesquiterpene from the marine alga, dawson
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