Chemoselective reduction of α,β-unsaturated ketones to allylic alcohols under catalyst-free conditions-Reference-Cited by-同舟云学术

Chemoselective reduction of α,β-unsaturated ketones to allylic alcohols under catalyst-free conditions

Published:2022 Issue:4 Volume:9 Page:1109-1114
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Jian Kaixia¹,Li Bingnan¹,Zhu Shuxian¹,Xuan Qingqing¹,Song Qiuling¹²³⁴^ORCID

Affiliation:

1. Institute of Next Generation Matter Transformation, College of Material Sciences Engineering at Huaqiao University, 668 Jimei Boulevard, Xiamen, Fujian, 361021, China

2. Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen 518055, Guangdong, China

3. State Key Laboratory of Organometallic Chemistry and Key Laboratory of Organo-fluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

4. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, 453007

Abstract

A strategy of chemoselective reduction of α, β-unsaturated ketones was developed in our group. H3N·BH3 would prefer to coordinate with CO bond, forming six-membered ring, and ketones were hydrogenated via concerted double-hydrogen-transfer process.

Funder

National Natural Science Foundation of China

Guangdong Provincial Key Laboratory Of Catalysis

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D1QO01754C

Reference65 articles.

1. R. A.Johnson and K. B.Sharpless , in Catalytic Asymmetric Synthesis , ed. I. Ojima , Wiley-VCH , Weinheim , 2000 , ch. 6A

2. T.Katsuki , in ComprehensiVe Asymmetric Catalysis , ed. E. N. Jacobsen , A. Pfaltz and H. Yamamoto , Springer , Berlin , 1999 , Vol. 2 , p. 621