Slow magnetic relaxation in a μ1,1′-azido cobalt(ii) methylquinoline chain complex-Reference-Cited by-同舟云学术

Slow magnetic relaxation in a μ1,1′-azido cobalt(ii) methylquinoline chain complex

Published:2018 Issue:44 Volume:47 Page:15745-15750
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rajnák Cyril¹²³⁴⁵^ORCID,Dlháň Ľubor⁶⁷⁸⁹⁵,Moncol Ján⁶⁷⁸⁹⁵,Titiš Ján¹²³⁴⁵^ORCID,Boča Roman¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Natural Sciences

3. University of SS Cyril and Methodius

4. 91701 Trnava

5. Slovakia

6. Institute of Inorganic Chemistry

7. FCHPT

8. Slovak University of Technology

9. 812 37 Bratislava

Abstract

A [Co(N₃)₂(mqu)] complex with a 1D chain architecture (mqu – 4-methylquinoline) shows slow magnetic relaxation with three distinct modes. The relaxation time strongly depends upon the applied external field. The low-frequency mode exhibits a relaxation time longer than one second: τ_LF = 1.6(2) s at B_DC = 0.8 T and T = 1.9 K.

Funder

European Regional Development Fund

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03351J

Reference35 articles.

1. 3d single-ion magnets