A novel sandwich shaped {CoIII2CoII12MoV24} cluster with a CoII4 triangle encapsulated in two capped CoIIICoII4MoV12O40 fragments-Reference-Cited by-同舟云学术

A novel sandwich shaped {CoIII2CoII12MoV24} cluster with a CoII4 triangle encapsulated in two capped CoIIICoII4MoV12O40 fragments

Published:2020 Issue:5 Volume:49 Page:1375-1379
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Hai-Ye¹²³⁴⁵,Pang Hua-Yu¹²³⁴⁵,Yao Peng-Fei¹²³⁴⁵,Huang Fu-Ping¹²³⁴⁵^ORCID,Bian He-Dong¹²³⁴⁵^ORCID,Liang Fu-Pei¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources

2. School of Chemistry and Pharmacy

3. Guangxi Normal University

4. Guilin 541004

5. P. R. China

Abstract

A novel discrete {Co₁₄Mo₂₄} nanoscaled cluster, with a triangle Co₄ core encapsulated in two novel capped Co-substituted Keggin-type Co₅Mo₁₂O₄₀ anions, was isolated from alkaline methanol solution. And the HRESI-MS of {Co₁₄Mo₂₄} cluster was recorded.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangxi Province

Guangxi Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04459K

Reference50 articles.

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4. [Ag48(C≡CtBu)20(CrO4)7]: An Atomically Precise Silver Nanocluster Co-protected by Inorganic and Organic Ligands

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