Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations-Reference-Cited by-同舟云学术

Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations

Published:2021 Issue:36 Volume:50 Page:12430-12434
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

do Pim Walace D.¹²^ORCID,Silva Ingrid F.¹^ORCID,da Silva Júnior Eufrânio N.¹^ORCID,Stumpf Humberto O.¹^ORCID,Oliveira Willian X. C.¹^ORCID,Pedroso Emerson F.²^ORCID,Pinheiro Carlos B.³^ORCID,Journaux Yves⁴^ORCID,Fantuzzi Felipe⁵⁶⁷^ORCID,Krummenacher Ivo⁶⁷^ORCID,Braunschweig Holger⁶⁷^ORCID,Engels Bernd⁵^ORCID,Cano Joan⁸^ORCID,Julve Miguel⁸^ORCID,Pereira Cynthia L. M.¹^ORCID

Affiliation:

1. Departamento de Química, Universidade Federal de Minas Gerais, Av. Antônio Carlos, 6627, Pampulha, Belo Horizonte, MG, 31270-901, Brazil

2. Departamento de Química, Centro Federal de Educação Tecnológica de Minas Gerais, Av. Amazonas, 5253, Belo Horizonte, MG, 30421-169, Brazil

3. Departamento de Física, Universidade Federal de Minas Gerais, Av. Antônio Carlos, 6627, Pampulha, Belo Horizonte, MG, 31270-901, Brazil

4. Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire, IPCM, 75252, Paris, France

5. Institut für Physikalische und Theoretische Chemie, Julius-Maximilians-Universität Würzburg, Emil-Fischer-Straße 42, 97074 Würzburg, Germany

6. Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

7. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

8. Instituto de Ciencia Molecular/Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain

Abstract

An unexpected heterobimetallic ring {CoII6CuII6} was synthesised by slow diffusion in water under ambient conditions and its dc magnetic properties were analysed through an effective Hamiltonian in the light of DFT type calculations.

Funder

Alexander von Humboldt-Stiftung

Royal Society of Chemistry

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Ministerio de Ciencia e Innovación

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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