Redox-enhanced hemilability of a tris(tert-butoxy)siloxy ligand at cerium
Author:
Affiliation:
1. Institut für Anorganische Chemie
2. Eberhard Karls Universität Tübingen
3. 72076 Tübingen
4. Germany
5. P. Roy and Diana T. Vagelos Laboratories
6. Department of Chemistry
7. University of Pennsylvania
8. Philadelphia
9. USA
Abstract
Combined structural/electrochemical/computational studies of ceric Ce[OSi(OtBu)3]4 and cerous [Ce{OSi(OtBu)3}4][K(2.2.2-crypt)] suggest a redox-modulated coordination switch of a tris(tert-butoxy)siloxy ligand.
Funder
National Science Foundation
Deutsche Forschungsgemeinschaft
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT01878B
Reference90 articles.
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4. Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes1
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