Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides-Reference-Cited by-同舟云学术

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

Published:2022 Issue:3 Volume:13 Page:681-691
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Willauer Aurélien R.¹^ORCID,Douair Iskander²,Chauvin Anne-Sophie¹^ORCID,Fadaei-Tirani Farzaneh¹^ORCID,Bünzli Jean-Claude G.¹³^ORCID,Maron Laurent²,Mazzanti Marinella¹^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

2. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077, Toulouse, France

3. Department of Biomedical Engineering, Southern University of Science and Technology (SUSTech), Shenzhen, China

Abstract

The first observed luminescence emission spectra of Pr(iv) complexes are assigned to a ligand-based emission. Binding of the triphenylsiloxide ligand to the Pr(iv) ion leads to an unprecedented large red shift of its triplet state.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC05517H

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