Approaching the 1000 K energy barrier in high coordinate lanthanide single-ion magnets: Increasing Ueff in the [Dy(Tp2-py)F]+ moiety with tetrahydrofuran-Reference-Cited by-同舟云学术

Approaching the 1000 K energy barrier in high coordinate lanthanide single-ion magnets: Increasing U_eff in the [Dy(Tp^2-py)F]⁺ moiety with tetrahydrofuran

Published:2024 Issue:22 Volume:53 Page:9252-9256
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Thomas Jarrod R.¹^ORCID,Giansiracusa Marcus J.²^ORCID,Sulway Scott A.¹^ORCID

Affiliation:

1. School of Chemistry, The University of New South Wales (UNSW), Kensington, Sydney, 2052, Australia

2. School of Chemistry, University of Melbourne, Parkville, Victoria, 3010, Australia

Abstract

The isolation of the solvated adduct [Dy(Tp2-py)F(THF)2]+, that supports a terminal dysprosium fluoride bond, presents the largest energy barrier for a high coordinate (n > 8), lanthanide-based Single-Ion Magnet.

Funder

University of New South Wales

University of Melbourne

Australian Research Council

Australian Nuclear Science and Technology Organisation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01194E

Reference22 articles.

1. A fluoride bridged {CrIII4DyIII4} single molecule magnet

2. Synthesis, Structures, and Magnetic Properties of Three Fluoride-Bridged Lanthanide Compounds: Effect of Bridging Fluoride Ions on Magnetic Behaviors

3. Slow Magnetic Relaxation Observed in Dysprosium Compounds Containing Unsupported Near-Linear Hydroxo- and Fluoro-Bridges

4. Lanthanide Complexes of the Hexadentate N-Donor Podand Tris[3-(2-pyridyl)pyrazolyl]hydroborate: Solid-State and Solution Properties

5. Synthesis of the new tripodal ligand tris-[3-(2′-pyridyl)pyrazol-1-yl]hydroborate, and the crystal structure of its europium(III) complex