A fluoride bridged {CrIII4DyIII4} single molecule magnet
Author:
Affiliation:
1. School of Chemistry
2. Monash University
3. Clayton
4. Australia
Abstract
Fluoride bridging between Dy⋯Dy neighbours in an octanuclear {CrIII4DyIII4} cluster of the ‘square-in-square’ structural type is the key reason for enhanced single molecule magnetic properties of Cr–Dy SMMs and, particularly, when compared to a reported azido bridged {CrIII4DyIII4} structural analogue.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03100H
Reference13 articles.
1. A {CrIII2DyIII2} Single-Molecule Magnet: Enhancing the Blocking Temperature through 3d Magnetic Exchange
2. Magnetic Exchange Effects in {CrIII2DyIII2} Single Molecule Magnets Containing Alcoholamine Ligands
3. Modulation of slow magnetic relaxation by tuning magnetic exchange in {Cr2Dy2} single molecule magnets
4. An Octanuclear [CrIII4DyIII4] 3d-4f Single-Molecule Magnet
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