Nitrene formation is the first step of the thermal and photochemical decomposition reactions of organic azides

Author:

Soto Juan1ORCID,Algarra Manuel2ORCID,Peláez Daniel3

Affiliation:

1. Department of Physical Chemistry, Faculty of Science, University of Málaga, E-29071 Málaga, Spain

2. INAMAT2 Institute for Advanced Materials and Mathematics, Department of Sciences, Campus de Arrosadia, 31006 Pamplona, Spain

3. Institut des Sciences Moléculaires d’Orsay (ISMO) - UMR 8214, Université Paris-Saclay, 91405 Orsay Cedex, Spain

Abstract

The first reaction step of the thermal or photochemical decomposition reactions of aliphatic azides yields a nitrene intermediate.

Funder

Junta de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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