Metal-free highly chemo-selective bisphosphorylation and deoxyphosphorylation of carboxylic acids-Reference-Cited by-同舟云学术

Metal-free highly chemo-selective bisphosphorylation and deoxyphosphorylation of carboxylic acids

Published:2023 Issue:20 Volume:14 Page:5519-5526
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gan Liguang¹,Xu Tianhao¹,Tan Qihang¹,Cen Mengjie¹,Wang Lingling¹,Zhao Jingwei¹,Liu Kuang¹,Liu Long¹,Chen Wen-Hao²,Han Li-Biao³^ORCID,Nycz Jacek E.⁴,Chen Tieqiao¹^ORCID

Affiliation:

1. Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou, 570228, China

2. Key Laboratory of Tropical Medicinal Resource Chemistry of Ministry of Education, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou, 571158, China

3. Zhejiang Yangfan New Materials Co. Ltd, Shangyu 312369, Zhejiang, China

4. Institute of Chemistry, Faculty of Science and Technology, University of Silesia in Katowice, ul. Szkolna 9, PL-40007 Katowice, Poland

Abstract

The bisphosphorylation and deoxyphosphorylation of carboxylic acids are achieved selectively under the metal-free reaction conditions. In addition, carboxylic acids can be further transformed into alkenes by coupling with WHE reaction of ketones and aldehydes.

Funder

National Natural Science Foundation of China

Key Research and Development Project of Hainan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01148H

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5. Asymmetric Brønsted acid catalysis with chiral carboxylic acids

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