Crystal-to-crystal polymerisation of monosubstituted [PW11O39Cu(H2O)]5− Keggin-type anions-Reference-Cited by-同舟云学术

Crystal-to-crystal polymerisation of monosubstituted [PW₁₁O₃₉Cu(H₂O)]⁵⁻ Keggin-type anions

Published:2024 Issue:21 Volume:53 Page:9042-9051
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ruiz-Bilbao Estibaliz¹²^ORCID,Pache Aroa¹,Barrenechea Unai¹,Reinoso Santiago³^ORCID,San Felices Leire⁴^ORCID,Vivanco Maria dM.⁵^ORCID,Lezama Luis¹^ORCID,Artetxe Beñat¹^ORCID,Gutiérrez-Zorrilla Juan M.¹²^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco UPV/EHU, P.O. Box 644, 48080 Bilbao, Spain

2. BCMaterials Edificio Martina Casiano, 3rd Floor, UPV/EHU Science Park, Barrio Sarriena s/n, 48940 Leioa, Spain

3. Institute for Advanced Materials and Mathematics (INAMAT2), Departamento de Ciencias, Universidad Pública de Navarra (UPNA), Campus de Arrosadia, 31006 Pamplona, Spain

4. Servicios Generales de Investigación SGIker, Facultad de Ciencia y Tecnología, Universidad del País Vasco UPV/EHU, P.O. Box 644, 48080 Bilbao, Spain

5. Cancer Heterogeneity Lab, Center for Cooperative Research in Biosciences (CIC bioGUNE), Basque Research and Technology Alliance (BRTA), Bizkaia Technology Park, 48160 Derio, Spain

Abstract

Compound [C(NH2)3]10[{PW11O39Cu(H2O)}2{Cu(pic)2}]·10H2O (1, pic = picolinate) undergoes a thermally-triggered single-crystal-to-single-crystal transformation that involves an unprecedented solid-state polymerisation of monosubstituted Keggin anions.

Funder

Ministerio de Ciencia e Innovación

Eusko Jaurlaritza

Euskal Herriko Unibertsitatea

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00690A

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