Structural transformation of metal–organic frameworks and identification of electrocatalytically active species during the oxygen evolution reaction under neutral conditions

Author:

Liang Xiaoqiang1ORCID,Wang Sen1,Feng Jingyu23ORCID,Xu Zhen24ORCID,Guo Zhenyu2ORCID,Luo Hui2ORCID,Zhang Feng5ORCID,Wen Chen6,Feng Lei6,Wan Chengan6,Titirici Maria-Magdalena2ORCID

Affiliation:

1. School of Environmental and Chemical Engineering, Xi'an Polytechnic University, 710048, Xi'an, PR China

2. Department of Chemical Engineering, Imperial College London, South Kensington Campus, SW7 2AZ, London, UK

3. School of Engineering and Materials Science, Queen Mary University of London, E1 4NS, London, UK

4. Yusuf Hamied Department of Chemistry, University of Cambridge, CB2 1EW, Cambridge, UK

5. Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, Heilongjiang Province and College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, PR China

6. Beijing Spacecrafts, 100094, Beijing, PR China

Abstract

Electrocatalytically active species of crystalline MOFs in a neutral OER process were identified as a mononuclear coordination compound and its isomer via a crystal-to-crystal transformation.

Funder

Natural Science Basic Research Program of Shaanxi Province

China Scholarship Council

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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