Isolated PdO sites on SiO<sub>2</sub>-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation-Reference-Cited by-同舟云学术

Isolated PdO sites on SiO₂-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Published:2023 Issue:12 Volume:13 Page:3483-3488
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Ziarko Aleksandra¹,Slater Thomas J. A.²^ORCID,Isaacs Mark A.³⁴^ORCID,Durndell Lee J.⁵^ORCID,Parlett Christopher M. A.⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Chemical Engineering and Applied Chemistry, Aston University, Birmingham, B4 7ET, UK

2. School of Chemistry, Cardiff University, Cardiff, CF10 3AT, UK

3. Department of Chemistry, University College London, London, WC1H 0AJ, UK

4. HarwellXPS, Research Complex at Harwell, RAL, Harwell Campus, Didcot, OX11 0FA, UK

5. School of Geography, Earth and Environmental Sciences, University of Plymouth, Plymouth, PL4 8AA, UK

6. Department of Chemical Engineering, University of Manchester, Manchester, M13 9PL, UK

7. University of Manchester at Harwell, Diamond Light Source, Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0DE, UK

8. Diamond Light Source, Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0DE, UK

9. UK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory, Oxfordshire, OX11 0FA, UK

Abstract

Silica-supported NiO nanoparticles as hosts for isolated PdO catalytic sites. Isolate PdO is confirmed as the species responsible for the chemoselective oxidation of cinnamyl alcohol to cinnamaldehyde by operando X-ray absorption spectroscopy.

Funder

Diamond Light Source

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00198A

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