Nanoporous polystyrene–porphyrin nanoparticles for selective gas separation
Author:
Affiliation:
1. Institute of Electronic Structure and Laser
2. Foundation for Research and Technology – Hellas
3. 711 10 Heraklion Crete
4. Greece
5. Department of Materials Science and Technology
6. University of Crete
7. 710 03 Heraklion Crete
Abstract
Highly cross-linked polystyrene nanoparticles bearing functional porphyrin moieties were synthesized by emulsion free-radical copolymerization. The polystyrene–porphyrin nanoparticles exhibit exceptionally high CO2/CH4 selectivity values, attributed to the presence of the porphyrin macrocyclic cavities in the material, which renders them attractive for use in gas separation and gas capture applications.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY00296J
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