Nanoporous polystyrene–porphyrin nanoparticles for selective gas separation

Author:

Flouraki Ch.12345,Kaliva M.12345,Papadas I. T.5674,Armatas G. S.5674,Vamvakaki M.12345

Affiliation:

1. Institute of Electronic Structure and Laser

2. Foundation for Research and Technology – Hellas

3. 711 10 Heraklion Crete

4. Greece

5. Department of Materials Science and Technology

6. University of Crete

7. 710 03 Heraklion Crete

Abstract

Highly cross-linked polystyrene nanoparticles bearing functional porphyrin moieties were synthesized by emulsion free-radical copolymerization. The polystyrene–porphyrin nanoparticles exhibit exceptionally high CO2/CH4 selectivity values, attributed to the presence of the porphyrin macrocyclic cavities in the material, which renders them attractive for use in gas separation and gas capture applications.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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