A well-defined nitro-functionalized aromatic framework (NO2-PAF-1) with high CO2 adsorption: synthesis via the copper-mediated Ullmann homo-coupling polymerization of a nitro-containing monomer
Author:
Affiliation:
1. School of Materials Science and Engineering
2. Beijing Institute of Technology
3. Beijing
4. China
5. The Biorefinery Research and Engineering Center
6. Institute of Coal Chemistry
7. Chinese Academy of Sciences
8. Taiyuan 030001
Abstract
A nitro group functionalized porous aromatic framework (NO2-PAF-1) was synthesized via a copper-mediated Ullmann reaction. Its CO2 uptake was higher that of PAF-1 due to the strong interaction of the nitro group with CO2.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2016/PY/C5PY01682G
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