Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium-Reference-Cited by-同舟云学术

Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium

Published:2020 Issue:21 Volume:49 Page:7015-7027
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gianino Jacqueline¹²³⁴⁵,Brown Seth N.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. 251 Nieuwland Science Hall

3. University of Notre Dame

4. Notre Dame

5. USA

Abstract

Describing the π bonding in ruthenium and osmium iminoxolenes as highly covalent allows one to experimentally dissect the electron distribution in these compounds.

Funder

Division of Chemistry

U.S. Department of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01287D

Reference52 articles.

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4. Electronic Structure of Bis(o-iminobenzosemiquinonato)metal Complexes (Cu, Ni, Pd). The Art of Establishing Physical Oxidation States in Transition-Metal Complexes Containing Radical Ligands

5. Redox activity and π bonding in a tripodal seven-coordinate molybdenum(vi) tris(amidophenolate)

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