Redox activity and π bonding in a tripodal seven-coordinate molybdenum(vi) tris(amidophenolate)-Reference-Cited by-同舟云学术

Redox activity and π bonding in a tripodal seven-coordinate molybdenum(vi) tris(amidophenolate)

Published:2015 Issue:2 Volume:44 Page:677-685
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Marshall-Roth Travis¹²³⁴,Brown Seth N.¹²³⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Notre Dame

3. Notre Dame

4. USA

Abstract

A tripodal seven-coordinate tris(amidophenolato)molybdenum(vi) complex shows strong ligand-to-metal π donation (40 kcal mol⁻¹ per π bond) and undergoes facile ligand-centered oxidation.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02936D

Reference98 articles.

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3. Trigonal Bi- and Monopyramidal Cobalt(II) Complexes of a Novel Guanidine-Based Tripodal Ligand

4. Titanium Amino Alcohol Complexes from α-Titanic Acid: X-Ray Crystal Structure of Titanium Bis[2,2´-(methylimino)diethanolate]

5. Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxidesElectronic supplementary information (ESI) available: syntheses and spectroscopic characterization of new compounds. See http://www.rsc.org/suppdata/cc/b3/b315092e/

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