Ni(<scp>ii</scp>) and Pd(<scp>ii</scp>) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(<scp>ii</scp>)-assisted intraligand cyclization forms a phenoxazinyl ring-Reference-Cited by-同舟云学术

Ni(ii) and Pd(ii) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(ii)-assisted intraligand cyclization forms a phenoxazinyl ring

Published:2024 Issue:33 Volume:53 Page:14046-14064
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bhowmik Saumitra¹^ORCID,Sengupta Arunava²^ORCID,Mukherjee Rabindranath³^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741246, India

2. Department of Chemistry and Chemical Biology, Indian Institute of Technology (ISM) Dhanbad, Dhanbad, Jharkhand 826004, India

3. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India

Abstract

Molecular and electronic structures of square planar complexes (1, [NiII{(LISQ)˙2−}], St = 1/2; 2, [PdII{(LISQ)˙2−}], St = 1/2; ) 3, [NiII{(LIBQ)−}]+/ 1+, St = 0); 4, [PdII{(L*AP)˙2−}]/ 2+ (phenoxazinyl ring formation), St = 1/2) are reported.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology

Indian Institute of Technology (Indian School of Mines), Dhanbad

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01513D

Reference78 articles.

1. Preface: Forum on Redox-Active Ligands

2. Preface for the Forum on Applications of Metal Complexes with Ligand-Centered Radicals

3. Non-innocent ligands in bioinorganic chemistry—An overview

4. Manifestations of Noninnocent Ligand Behavior

5. Non-innocent behaviour in mononuclear and polynuclear complexes: consequences for redox and electronic spectroscopic properties