Photocatalytic hydrogen evolution using a Ru(ii)-bound heteroaromatic ligand as a reactive site

Author:

Sawaki Takuya12345,Ishizuka Tomoya12345ORCID,Namura Nanase12345,Hong Dachao12345ORCID,Miyanishi Mayuko6785,Shiota Yoshihito6785,Kotani Hiroaki12345ORCID,Yoshizawa Kazunari6785ORCID,Jung Jieun9101112,Fukuzumi Shunichi910111213ORCID,Kojima Takahiko12345ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Pure and Applied Sciences

3. University of Tsukuba and CREST (JST)

4. Tsukuba

5. Japan

6. Institute for Materials Chemistry and Engineering

7. Kyushu University

8. Fukuoka 819-0395

9. Department of Chemistry and Nano Science

10. Ewha Womans University

11. Seoul 120-750

12. South Korea

13. Faculty of Science and Technology

Abstract

A RuII complex with a π-expanded diimine ligand performs photocatalytic H2 evolution and hydrogenation of organic substrates under visible-light irradiation, involving an intermediate with the dihydrogenated ligand; a mechanistic insight into the H2 evolution is also gained.

Funder

Japan Society for the Promotion of Science

Mitsubishi Foundation

Yazaki Memorial Foundation for Science and Technology

Ministry of Education, Culture, Sports, Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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