Photocatalytic hydrogen evolution using a Ru(ii)-bound heteroaromatic ligand as a reactive site-Reference-Cited by-同舟云学术

Photocatalytic hydrogen evolution using a Ru(ii)-bound heteroaromatic ligand as a reactive site

Published:2020 Issue:47 Volume:49 Page:17230-17242
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sawaki Takuya¹²³⁴⁵,Ishizuka Tomoya¹²³⁴⁵^ORCID,Namura Nanase¹²³⁴⁵,Hong Dachao¹²³⁴⁵^ORCID,Miyanishi Mayuko⁶⁷⁸⁵,Shiota Yoshihito⁶⁷⁸⁵,Kotani Hiroaki¹²³⁴⁵^ORCID,Yoshizawa Kazunari⁶⁷⁸⁵^ORCID,Jung Jieun⁹¹⁰¹¹¹²,Fukuzumi Shunichi⁹¹⁰¹¹¹²¹³^ORCID,Kojima Takahiko¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Pure and Applied Sciences

3. University of Tsukuba and CREST (JST)

4. Tsukuba

5. Japan

6. Institute for Materials Chemistry and Engineering

7. Kyushu University

8. Fukuoka 819-0395

9. Department of Chemistry and Nano Science

10. Ewha Womans University

11. Seoul 120-750

12. South Korea

13. Faculty of Science and Technology

Abstract

A Ru^II complex with a π-expanded diimine ligand performs photocatalytic H₂ evolution and hydrogenation of organic substrates under visible-light irradiation, involving an intermediate with the dihydrogenated ligand; a mechanistic insight into the H₂ evolution is also gained.

Funder

Japan Society for the Promotion of Science

Mitsubishi Foundation

Yazaki Memorial Foundation for Science and Technology

Ministry of Education, Culture, Sports, Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03546G