Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl-Reference-Cited by-同舟云学术

Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl

Published:2015 Issue:2 Volume:6 Page:917-922
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hwang Seung Jun¹²³,Powers David C.¹²³,Maher Andrew G.¹²³⁴⁵,Nocera Daniel G.¹²³

Affiliation:

1. Department of Chemistry and Chemical Biology

2. Cambridge

3. USA

4. Department of Chemistry

5. Massachusetts Institute of Technology

Abstract

The challenge that short excited state lifetimes of first-row transition metal complexes present to the photoactivation of M–X bonds has been overcome with a phosphine mediator coupled to a nickel metal catalyst.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02357A

Reference46 articles.

1. Hydrogen Production by Molecular Photocatalysis

2. Chemistry of Personalized Solar Energy

3. Hydrogen Produced from Hydrohalic Acid Solutions by a Two-Electron Mixed-Valence Photocatalyst

4. A Photocycle for Hydrogen Production from Two-Electron Mixed-Valence Complexes

5. Stability-enhanced hydrogen-evolving dirhodium photocatalysts through ligand modification

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