Elimination of light-induced degradation at the nickel oxide-perovskite heterojunction by aprotic sulfonium layers towards long-term operationally stable inverted perovskite solar cells

Author:

Wu Tianhao1,Ono Luis K.1ORCID,Yoshioka Rengo2,Ding Chenfeng1,Zhang Congyang1,Mariotti Silvia1,Zhang Jiahao1,Mitrofanov Kirill2,Liu Xiao3,Segawa Hiroshi3,Kabe Ryota2ORCID,Han Liyuan34ORCID,Qi Yabing1ORCID

Affiliation:

1. Energy Materials and Surface Sciences Unit (EMSSU), Okinawa Institute of Science and Technology Graduate University (OIST), 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan

2. Organic Optoelectronics Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami-gun, Okinawa 904-0495, Japan

3. Special Division of Environmental and Energy Science, Komaba Organization for Educational Excellence (KOMEX), College of Arts and Sciences, University of Tokyo, Tokyo 153-8902, Japan

4. State Key Laboratory of Metal Matrix Composites, School of Material Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Abstract

This work introduces an aprotic sulfonium buffer layer at the nickel oxide–perovskite heterojunction to eliminate the multi-step photochemical reactions, which leads to inverted perovskite solar cells with long-term operational stability.

Funder

National Natural Science Foundation of China

Okinawa Institute of Science and Technology Graduate University

Japan Science and Technology Corporation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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