Aromatic–hydroxyl interaction of an alpha-aryl ether lignin model-compound on SBA-15, present at pyrolysis temperatures
Author:
Affiliation:
1. Chemical Sciences Division
2. Oak Ridge National Laboratory
3. Oak Ridge, USA
4. Center for Nanophase Materials Sciences
Abstract
BPEa hydrogen bonds to SBA-15 surface hydroxylsviaan aromatic–hydroxyl interaction characterized by a redshift of >100 cm−1in the OH and CH vibrational frequencies. Surprisingly, this aromatic–hydroxyl interaction is present until ∼400 °C.
Funder
U.S. Department of Energy
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP02633K
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