Reactive species involved in the regioselective photooxidation of heptamethine cyanines-Reference-Cited by-同舟云学术

Reactive species involved in the regioselective photooxidation of heptamethine cyanines

Published:2015 Issue:11 Volume:6 Page:6556-6563
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nani Roger R.¹²³⁴⁵,Kelley James A.¹²³⁴⁵,Ivanic Joseph⁶⁷⁸⁴⁵,Schnermann Martin J.¹²³⁴⁵

Affiliation:

1. Chemical Biology Laboratory

2. Center for Cancer Research

3. National Cancer Institute at Frederick

4. Frederick

5. USA

6. Advanced Biomedical Computing Center

7. DSITP

8. Frederick National Laboratory for Cancer Research

Abstract

Experimental and computational studies indicate that the photodegradation of heptamethine cyanines proceeds via a regioselective photooxidative C–C cleavage reaction involving singlet oxygen and dioxetane intermediates.

Funder

National Cancer Institute

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02396C

Reference61 articles.

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2. Cyanine dyes in biophysical research: the photophysics of polymethine fluorescent dyes in biomolecular environments

3. Ultra-stable organic fluorophores for single-molecule research

4. Mechanisms of photobleaching investigated by fluorescence correlation spectroscopy

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